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Reply to Comments on “Synthesis, Characterization, and Structures of Persistent Aniline Radical Cation”
Author(s) -
Chen Xiaoyu,
Wang Xingyong,
Sui Yunxia,
Li Yizhi,
Ma Jing,
Zuo Jinglin,
Wang Xinping
Publication year - 2014
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201308539
Subject(s) - aniline , electron paramagnetic resonance , radical ion , chemistry , radical , characterization (materials science) , crystal structure , crystallography , medicinal chemistry , polymer chemistry , organic chemistry , materials science , ion , nuclear magnetic resonance , nanotechnology , physics
The identification of the aniline radical cation TBA .+ (TBA=2,4,6‐ t Bu 3 C 6 H 2 NH 2 ) reported in 2012 was questioned in the preceeding Correspondence articles. The original authors have reexamined their UV/Vis absorption and EPR data and insist that TBA .+ radical cation is indeed persistent and stable. The possible cocrystallization of TBA .+ with TBAH + makes crystal structures more complicated.
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