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SF and SC Activation of SF 6 and SF 5 Derivatives at Rhodium: Conversion of SF 6 into H 2 S
Author(s) -
Zámostná Lada,
Braun Thomas,
Braun Beatrice
Publication year - 2014
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201308254
Subject(s) - rhodium , chemistry , x ray crystallography , nuclear magnetic resonance spectroscopy , spectroscopy , crystallography , catalysis , diffraction , stereochemistry , organic chemistry , physics , quantum mechanics , optics
The degradation of SF 6 and SF 5 organyls by SF and SC bond‐activation reactions at [{Rh(μ‐H)(dippp)} 2 ] under mild conditions is reported. Fluorido and thiolato species were identified as products or intermediates, and were characterized by X‐ray diffraction analysis and multinuclear NMR spectroscopy. An unprecedented cyclic process for the conversion of the potent greenhouse gas SF 6 into H 2 S was developed.