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Approaching White‐Light Emission from a Phosphorescent Trinuclear Gold(I) Cluster by Modulating Its Aggregation Behavior
Author(s) -
Ni WenXiu,
Li Mian,
Zheng Ji,
Zhan ShunZe,
Qiu YuMin,
Ng Seik Weng,
Li Dan
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201308135
Subject(s) - stacking , phosphorescence , chromophore , white light , cluster (spacecraft) , aggregation induced emission , red light , white (mutation) , orange (colour) , blue light , photochemistry , materials science , chemistry , optoelectronics , optics , physics , computer science , fluorescence , organic chemistry , biochemistry , botany , gene , biology , programming language , food science
White light : [{Au( L )} 3 ] ( L =3‐(2‐thienyl)pyrazolate) gives dual emission, one from an organic chromophore the other from aurophilic stacking interactions. The resulting blue–green and orange–red emissions can be tuned to approach white‐light by modulating the aggregation behavior of the cluster.