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A Domino Approach to Dibenzopentafulvalenes by Quadruple Carbopalladation
Author(s) -
Wallbaum Jan,
Neufeld Roman,
Stalke Dietmar,
Werz Daniel B.
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201307793
Subject(s) - domino , chemistry , stereochemistry , crystallography , combinatorial chemistry , organic chemistry , catalysis
Four at one stroke : A quadruple domino carbopalladation reaction gives access to highly substituted dibenzopentafulvalenes and the complete pentafulvalene backbone is constructed in only one synthetic step. Structural and electronic properties have been evaluated by X‐ray crystallography and cyclovoltammetry.