1,1‐Carbozirconation: Unusual Reaction of an Alkyne with a Methyl Zirconocene Cation and Subsequent Frustrated Lewis Pair Like Reactivity | Zendy

Xu Xin | Zendy; Kehr Gerald | Zendy; Daniliuc Constantin G. | Zendy; Erker Gerhard | Zendy

Premium

1,1‐Carbozirconation: Unusual Reaction of an Alkyne with a Methyl Zirconocene Cation and Subsequent Frustrated Lewis Pair Like Reactivity

Author(s) -

Xu Xin,

Kehr Gerald,

Daniliuc Constantin G.,

Erker Gerhard

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201307493

Subject(s) - alkyne , reactivity (psychology) , frustrated lewis pair , chemistry , trimethylsilyl , lewis acids and bases , medicinal chemistry , boron , vicinal , acetylene , organic chemistry , catalysis , medicine , alternative medicine , pathology

Boron chemistry without the boron : In a reaction analogous to 1,1‐carboboration, [Cp* 2 ZrCH 3 ] + reacts with diphenylphosphino(trimethylsilyl)acetylene by 1,1‐carbozirconation to give a vicinal [Zr] + /P system. Like B/P frustrated Lewis pairs, the [Zr] + /P system undergoes 1,2‐addition to unsaturated compounds (including CO 2 ) and reaction with metal complexes and up to three equivalents of CO.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research