Bidirectional Regulation of Halide Binding in a Heterometallic Supramolecular Cube | Zendy

Ramsay William J. | Zendy; Ronson Tanya K. | Zendy; Clegg Jack K. | Zendy; Nitschke Jonathan R. | Zendy

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Bidirectional Regulation of Halide Binding in a Heterometallic Supramolecular Cube

Author(s) -

Ramsay William J.,

Ronson Tanya K.,

Clegg Jack K.,

Nitschke Jonathan R.

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201307478

Subject(s) - halide , cube (algebra) , cationic polymerization , supramolecular chemistry , chemistry , computer science , nanotechnology , crystallography , materials science , inorganic chemistry , polymer chemistry , mathematics , combinatorics , crystal structure

Complex cubes : In a cationic supramolecular cube, coordinatively unsaturated metal centers in the walls of the host provided binding sites for neutral or negatively charged guests. The binding of an initial guest (CF 3 CO 2 − , OPMe 3 , NH 3 , or NMe 3 ) either cooperatively enhanced or competitively inhibited the binding of a second guest (halide ion).

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