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Carbonylation of Cyclotrisilenes
Author(s) -
Cowley Michael J.,
Ohmori Yu,
Huch Volker,
Ichinohe Masaaki,
Sekiguchi Akira,
Scheschkewitz David
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201307450
Subject(s) - carbonylation , carbon monoxide , yield (engineering) , service (business) , computer science , product (mathematics) , substitution (logic) , chemistry , information retrieval , world wide web , organic chemistry , business , physics , mathematics , catalysis , programming language , thermodynamics , marketing , geometry
Spontaneous reaction of carbon monoxide with cyclotrisilenes has been observed. Depending on the substitution pattern, the initial product of carbonylation either dimerizes or can be trapped to yield highly functionalized cyclic silenes.