Metal Oxychlorides as Cathode Materials for Chloride Ion Batteries | Zendy

Zhao Xiangyu | Zendy; ZhaoKarger Zhirong | Zendy; Wang Di | Zendy; Fichtner Maximilian | Zendy

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Metal Oxychlorides as Cathode Materials for Chloride Ion Batteries

Author(s) -

Zhao Xiangyu,

ZhaoKarger Zhirong,

Wang Di,

Fichtner Maximilian

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201307314

Subject(s) - cathode , intercalation (chemistry) , electrochemistry , electrolyte , chloride , ion , key (lock) , chemistry , inorganic chemistry , materials science , computer science , electrode , metallurgy , organic chemistry , computer security

A key challenge of chloride ion batteries is to develop cathode materials that are stable in the electrolytes. Metal oxychlorides are presented as such a cathode material. The electrochemical performance and the reaction mechanisms of the BiOCl and FeOCl cathode were investigated. Both cathodes showed reversible reactions, including a major conversion reaction and a minor intercalation process, by chloride ion transfer during cycling.

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