N ‐Oxide as a Traceless Oxidizing Directing Group: Mild Rhodium(III)‐Catalyzed CH Olefination for the Synthesis of  ortho ‐Alkenylated Tertiary Anilines | Zendy

Huang Xiaolei | Zendy; Huang Jingsheng | Zendy; Du Chenglong | Zendy; Zhang Xingyi | Zendy; Song Feijie | Zendy; You Jingsong | Zendy

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N ‐Oxide as a Traceless Oxidizing Directing Group: Mild Rhodium(III)‐Catalyzed CH Olefination for the Synthesis of ortho ‐Alkenylated Tertiary Anilines

Author(s) -

Huang Xiaolei,

Huang Jingsheng,

Du Chenglong,

Zhang Xingyi,

Song Feijie,

You Jingsong

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201307174

Subject(s) - oxidizing agent , rhodium , group (periodic table) , chemistry , catalysis , service (business) , oxide , protocol (science) , combinatorial chemistry , computer science , library science , organic chemistry , business , medicine , alternative medicine , pathology , marketing

Double role : A traceless directing group also acts as an internal oxidant in a novel Rh III ‐catalyzed protocol developed for the synthesis of ortho ‐alkenylated tertiary anilines (see scheme). A five‐membered cyclometalated Rh III complex is proposed as a plausible intermediate and confirmed by X‐ray crystallographic analysis.

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