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B 2 S 2 O 9 : A Boron Sulfate with Phyllosilicate Topology
Author(s) -
Logemann Christian,
Wickleder Mathias S.
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201307056
Subject(s) - boron , sulfate , tetrahedron , topology (electrical circuits) , suite , computer science , binary number , service (business) , crystallography , chemistry , combinatorics , mathematics , arithmetic , organic chemistry , business , geography , archaeology , marketing
So many tetrahedra : The condensation of [BO 4 ] (orange) and [SO 4 ] (yellow) tetrahedra in the first binary boron sulfate B 2 S 2 O 9 , leads to a structure with typical layered phyllosilicate topology. The compound is obtained from the hydrolysis of B(OH) 3 and HSO 3 Cl.