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The Photoredox‐Catalyzed Meerwein Addition Reaction: Intermolecular Amino‐Arylation of Alkenes
Author(s) -
Prasad Hari Durga,
Hering Thea,
König Burkhard
Publication year - 2014
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201307051
Subject(s) - intermolecular force , photoredox catalysis , chemistry , catalysis , aryl , combinatorial chemistry , substrate (aquarium) , functional group , scope (computer science) , photochemistry , organic chemistry , molecule , photocatalysis , computer science , biology , polymer , alkyl , ecology , programming language
A variety of amides are efficiently accessible under mild conditions by intermolecular amino‐arylation using a photo Meerwein addition with visible light. The reaction has a broad substrate scope, tolerates a large range of functional groups, and was applied to the synthesis of a 3‐aryl‐3,4‐dihydroisoquinoline.