Formal Ring‐Opening/Cross‐Coupling Reactions of 2‐Pyrones: Iron‐Catalyzed Entry into Stereodefined Dienyl Carboxylates | Zendy

Sun ChangLiang | Zendy; Fürstner Alois | Zendy

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Formal Ring‐Opening/Cross‐Coupling Reactions of 2‐Pyrones: Iron‐Catalyzed Entry into Stereodefined Dienyl Carboxylates

Author(s) -

Sun ChangLiang,

Fürstner Alois

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201307028

Subject(s) - sophistication , catalysis , ring (chemistry) , coupling reaction , chemistry , diene , coupling (piping) , combinatorial chemistry , scheme (mathematics) , organic chemistry , materials science , mathematics , mathematical analysis , social science , natural rubber , sociology , metallurgy

Open access : Despite the exceptional level of sophistication in cross‐coupling chemistry, reactions of substrates that incorporate the leaving group as an integral part into a heterocyclic scaffold are scarce. The title reaction outlines the utility of this reaction format (see scheme; acac=acetylacetonate), provides a convenient entry into stereodefined diene carboxylates, and adds a new chapter to the field of iron catalysis.

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