Chiral‐at‐Metal Octahedral Iridium Catalyst for the Asymmetric Construction of an All‐Carbon Quaternary Stereocenter | Zendy

Chen LiangAn | Zendy; Tang Xiaojuan | Zendy; Xi Jianwei | Zendy; Xu Weici | Zendy; Gong Lei | Zendy; Meggers Eric | Zendy

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Chiral‐at‐Metal Octahedral Iridium Catalyst for the Asymmetric Construction of an All‐Carbon Quaternary Stereocenter

Author(s) -

Chen LiangAn,

Tang Xiaojuan,

Xi Jianwei,

Xu Weici,

Gong Lei,

Meggers Eric

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201306997

Subject(s) - stereocenter , enantioselective synthesis , iridium , chirality (physics) , octahedron , chemistry , catalysis , combinatorial chemistry , computer science , organic chemistry , crystal structure , physics , chiral symmetry breaking , quantum mechanics , quark , nambu–jona lasinio model

Metal‐templated organocatalysis : The enantioselective formation of an all‐carbon quaternary stereocenter is catalyzed by the ligand sphere of an inert bis‐cyclometalated iridium complex (see picture). In this complex, the metal‐centered chirality serves as the sole source for the effective asymmetric induction.

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