A Cerium(IV)–Carbon Multiple Bond | Zendy

Gregson Matthew | Zendy; Lu Erli | Zendy; McMaster Jonathan | Zendy; Lewis William | Zendy; Blake Alexander J. | Zendy; Liddle Stephen T. | Zendy

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A Cerium(IV)–Carbon Multiple Bond

Author(s) -

Gregson Matthew,

Lu Erli,

McMaster Jonathan,

Lewis William,

Blake Alexander J.,

Liddle Stephen T.

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201306984

Subject(s) - cerium , carbene , lanthanide , decomposition , chemistry , carbon fibers , computer science , catalysis , inorganic chemistry , organic chemistry , algorithm , ion , composite number

Straightforward access to a cerium(IV)–carbene complex was provided by one‐electron oxidation of an anionic “ate” cerium(III)–carbene precursor, thereby avoiding decomposition reactions that plague oxidations of neutral cerium(III) compounds. The cerium(IV)–carbene complex is the first lanthanide(IV)–element multiple bond and involves a twofold bonding interaction of two electron pairs between cerium and carbon.

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