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Synthesis of Five‐Membered Osmacycloallenes and Conversion into Six‐Membered Osmacycloallenes
Author(s) -
Wang Tongdao,
Zhu Jun,
Han Feifei,
Zhou Chen,
Chen Hanyu,
Zhang Hong,
Xia Haiping
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201306911
Subject(s) - ring (chemistry) , service (business) , computer science , transition (genetics) , information retrieval , chemistry , world wide web , organic chemistry , business , marketing , biochemistry , gene
Highly stable five‐membered metallacycloallenes were synthesized under mild conditions. Calculations revealed that the incorporation of transition‐metal moieties relieves considerable strain and indicates a trend toward ring enlargement in the five‐membered metallacycloallenes. Conversion into six‐membered metallacycloallenes was confirmed experimentally.