NHC‐Stabilized Silagermenylidene: A Heavier Analogue of Vinylidene | Zendy

Jana Anukul | Zendy; Huch Volker | Zendy; Scheschkewitz David | Zendy

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NHC‐Stabilized Silagermenylidene: A Heavier Analogue of Vinylidene

Author(s) -

Jana Anukul,

Huch Volker,

Scheschkewitz David

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201306780

Subject(s) - synthon , phenylacetylene , class (philosophy) , cycloaddition , computer science , chemistry , combinatorial chemistry , medicinal chemistry , stereochemistry , organic chemistry , artificial intelligence , catalysis

Stable vinylidene analogue : The synthesis of the first representative of a new compound class of low‐valent Group 14 elements, namely silagermenylidene A , is achieved by reduction of Tip 2 SiCl 2 and NHC⋅GeCl 2 (Tip=2,4,6‐ i Pr 3 C 6 H 2 ; NHC=1,3‐diisopropyl‐4,5‐dimethylimidazol‐2‐ylidene). The potential of A as a synthon is demonstrated by the formal [2+2] cycloaddition with phenylacetylene to afford NHC‐stabilized cyclic germylene B .

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