[3]Dendralene Synthesis: Rhodium(III)‐Catalyzed Alkenyl CH Activation and Coupling Reaction with Allenyl Carbinol Carbonate | Zendy

Wang Honggen | Zendy; Beiring Bernhard | Zendy; Yu DaGang | Zendy; Collins Karl D. | Zendy; Glorius Frank | Zendy

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[3]Dendralene Synthesis: Rhodium(III)‐Catalyzed Alkenyl CH Activation and Coupling Reaction with Allenyl Carbinol Carbonate

Author(s) -

Wang Honggen,

Beiring Bernhard,

Yu DaGang,

Collins Karl D.,

Glorius Frank

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201306754

Subject(s) - rhodium , catalysis , stereoselectivity , chemistry , coupling reaction , carbonate , medicinal chemistry , reaction conditions , functional group , coupling (piping) , combinatorial chemistry , organic chemistry , materials science , metallurgy , polymer

[3]DendrAl(l)ene! A new synthesis of [3]dendralenes is based on a Rh III ‐catalyzed alkenyl CH activation and coupling reaction with allenyl carbinol carbonates (see scheme; DG=directing group). A variety of [3]dendralenes with diverse substitution patterns are accessible with good efficiency. The reaction is highly stereoselective and compatible with different directing groups and numerous functional groups.

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