Using Monovalent Phosphorus Compounds to Form P–C Bonds | Zendy

Ng Yong Xiang | Zendy; Mathey Francois | Zendy

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Using Monovalent Phosphorus Compounds to Form P–C Bonds

Author(s) -

Ng Yong Xiang,

Mathey Francois

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201306643

Subject(s) - phosphinidene , electrophile , chemistry , phosphine , aryl , phosphorus , medicinal chemistry , electrophilic addition , stereochemistry , combinatorial chemistry , organic chemistry , catalysis , alkyl

User friendly P–C : Electrophilic terminal phosphinidene complexes [RPW(CO) 5 ] react with ArB(OH) 2 to give the corresponding secondary phosphine complexes [{R(Ar)PH}W(CO) 5 ]. This method enables the formation of PC bonds through the combination of a wide array of heterocyclic and aryl boronic acids with various electrophilic phosphinidene complexes. The final products incorporate a PH bond that can be used for further transformations.

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