A Controllable Gate Effect in Cobalt(II) Organic Frameworks by Reversible Structure Transformations | Zendy

Chen Qiang | Zendy; Chang Ze | Zendy; Song WeiChao | Zendy; Song Han | Zendy; Song HaiBin | Zendy; Hu TongLiang | Zendy; Bu XianHe | Zendy

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A Controllable Gate Effect in Cobalt(II) Organic Frameworks by Reversible Structure Transformations

Author(s) -

Chen Qiang,

Chang Ze,

Song WeiChao,

Song Han,

Song HaiBin,

Hu TongLiang,

Bu XianHe

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201306304

Subject(s) - metal organic framework , cobalt , encapsulation (networking) , computer science , transformation (genetics) , solvent , molecule , materials science , nanotechnology , topology (electrical circuits) , process engineering , chemistry , computer network , organic chemistry , electrical engineering , engineering , biochemistry , adsorption , gene

With H 2 O or NH 3 stimuli , the blue cobalt‐based metal–organic framework (MOF) BP can reversibly transform to red RP. The removal/recovery of terephthalate ligands accompanied by the transformation leads to a gate effect, which allows the encapsulation and release of small solvent molecules under certain conditions. This is the first example of topology transformation from a self‐penetrating to interpenetrating net in 3D MOFs.

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