Silver‐Catalyzed Hydrogenation of Aldehydes in Water | Zendy

Jia Zhenhua | Zendy; Zhou Feng | Zendy; Liu Mingxin | Zendy; Li Xingshu | Zendy; Chan Albert S. C. | Zendy; Li ChaoJun | Zendy

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Silver‐Catalyzed Hydrogenation of Aldehydes in Water

Author(s) -

Jia Zhenhua,

Zhou Feng,

Liu Mingxin,

Li Xingshu,

Chan Albert S. C.,

Li ChaoJun

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201306243

Subject(s) - catalysis , phosphine , denticity , chemistry , ligand (biochemistry) , organic chemistry , silver bullet , materials science , metal , biochemistry , receptor , metallurgy

Silver bullet : The first silver‐catalyzed hydrogenation in water was developed. A silver complex containing a bulky monodentate phosphine ligand was used to generate alcohols from a broad range of aldehydes, including aliphatic, aromatic, and heterocyclic aldehydes. This method provides a direct and efficient route to alcohols from aldehydes and opens a new avenue in silver catalysis.

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