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Enhanced Reactivity of a Biomimetic Iron(II) α‐Keto Acid Complex through Immobilization on Functionalized Gold Nanoparticles
Author(s) -
Sheet Debobrata,
Halder Partha,
Paine Tapan Kanti
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201305994
Subject(s) - decarboxylation , nanoparticle , colloidal gold , reactivity (psychology) , combinatorial chemistry , chemistry , ligand (biochemistry) , benzoic acid , nanotechnology , organic chemistry , materials science , catalysis , biochemistry , receptor , medicine , alternative medicine , pathology
Immobilized biomimetic iron complex : An iron(II) benzoylformate complex of a thiol‐appended N 4 ligand immobilized on gold nanoparticles activates dioxygen to carry out oxidative decarboxylation of benzoylformic acid to benzoic acid catalytically.