Rhodium(III)‐Catalyzed Azidation and Nitration of Arenes by CH Activation | Zendy

Xie Fang | Zendy; Qi Zisong | Zendy; Li Xingwei | Zendy

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Rhodium(III)‐Catalyzed Azidation and Nitration of Arenes by CH Activation

Author(s) -

Xie Fang,

Qi Zisong,

Li Xingwei

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201305902

Subject(s) - hypervalent molecule , chemistry , nitration , sodium azide , combinatorial chemistry , iodine , catalysis , pyridine , pyrazole , functional group , rhodium , pyrimidine , hydroxylamine , computer science , organic chemistry , stereochemistry , polymer

Getting a handle on it : In the chelation‐assisted title reactions in the presence of a hypervalent iodine oxidant, sodium azide and sodium nitrite served as readily available nitrogen sources, and pyridine, pyrimidine, and pyrazole substituents were efficient directing groups (DGs; see scheme; Cp*=C 5 Me 5 ). The synthetic utility of the azidation products was demonstrated in subsequent functional‐group transformations.

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