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Palladium(II)‐Catalyzed Direct Conversion of Methyl Arenes into Aromatic Nitriles
Author(s) -
Shu Zhibin,
Ye Yuxuan,
Deng Yifan,
Zhang Yan,
Wang Jianbo
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201305731
Subject(s) - nitrile , catalysis , palladium , ammoxidation , nitrite , chemistry , organic chemistry , combinatorial chemistry , computer science , acrylonitrile , polymer , nitrate , copolymer
From methyl to nitrile : A mild ammoxidation method, which directly converts methyl arenes into aromatic nitriles, has been developed by using Pd(OAc) 2 and N ‐hydroxyphthalimide (NHPI) as the catalysts, and tert ‐butyl nitrite as the nitrogen source and oxidant.