Catalytic Enantioselective Synthesis of Tertiary Thiols From 5 H ‐Thiazol‐4‐ones and Nitroolefins: Bifunctional Ureidopeptide‐Based Brønsted Base Catalysis | Zendy

Diosdado Saioa | Zendy; Etxabe Julen | Zendy; Izquierdo Joseba | Zendy; Landa Aitor | Zendy; Mielgo Antonia | Zendy; Olaizola Iurre | Zendy; López Rosa | Zendy; Palomo Claudio | Zendy

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Catalytic Enantioselective Synthesis of Tertiary Thiols From 5 H ‐Thiazol‐4‐ones and Nitroolefins: Bifunctional Ureidopeptide‐Based Brønsted Base Catalysis

Author(s) -

Diosdado Saioa,

Etxabe Julen,

Izquierdo Joseba,

Landa Aitor,

Mielgo Antonia,

Olaizola Iurre,

López Rosa,

Palomo Claudio

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201305644

Subject(s) - bifunctional , enantioselective synthesis , catalysis , brønsted–lowry acid–base theory , base (topology) , chemistry , organic chemistry , combinatorial chemistry , mathematics , mathematical analysis

Fully loaded : The ureidopeptide‐based bifunctional Brønsted base 1 efficiently promotes the first direct catalytic Michael reaction of α‐mercapto carboxylate surrogates with nitroolefins involving a fully substituted α‐carbon atom construction.

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