Premium
Strongly Phosphorescent Palladium(II) Complexes of Tetradentate Ligands with Mixed Oxygen, Carbon, and Nitrogen Donor Atoms: Photophysics, Photochemistry, and Applications
Author(s) -
Chow Pui Keong,
Ma Chensheng,
To WaiPong,
Tong Glenna So Ming,
Lai ShiuLun,
Kui Steven C. F.,
Kwok WaiMing,
Che ChiMing
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201305590
Subject(s) - phosphorescence , palladium , excited state , photochemistry , chemistry , oled , variety (cybernetics) , combinatorial chemistry , computer science , catalysis , organic chemistry , fluorescence , physics , atomic physics , quantum mechanics , layer (electronics) , artificial intelligence
A healthy glow : A series of palladium(II) complexes with tetradentate O N C N ligands (see structure) exhibit intense green phosphorescence and long‐lived excited states with emission quantum yields and lifetimes up to 22 % and 122 μs, respectively. The complexes show potential as novel functional materials, with promising results in a variety of applications, such as oxygen sensing, photocatalysis, and organic light‐emitting diodes.