[5,6]‐Open Methanofullerene Derivatives of  I h  ‐C 80 | Zendy

Izquierdo Marta | Zendy; Cerón Maira R. | Zendy; Olmstead Marilyn M. | Zendy; Balch Alan L. | Zendy; Echegoyen Luis | Zendy

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[5,6]‐Open Methanofullerene Derivatives of I h ‐C 80

Author(s) -

Izquierdo Marta,

Cerón Maira R.,

Olmstead Marilyn M.,

Balch Alan L.,

Echegoyen Luis

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201305476

Subject(s) - adduct , stoichiometry , cyclopropanation , chemistry , crystallography , polymer chemistry , catalysis , medicinal chemistry , materials science , organic chemistry

Newcomers on the scene : The modification of endohedral metallofullerenes with an I h ‐C 80 cage by cyclopropanation‐type addition reactions generally yields the [6,6] methanofullerene adducts. Now [5,6]‐open methanofullerenes with an I h ‐C 80 ‐derived cage have been synthesized, as confirmed by X‐ray crystallography, under relatively mild, stoichiometric conditions along with the corresponding [6,6]‐open derivatives in good yields.

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