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An Unstable Paramagnetic Isopolyoxomolybdate Intermediate Non‐Homogeneously Reduced at Different Sites and Trapped in a Host Based on Chemical Adaptability
Author(s) -
Merca Alice,
Garai Somenath,
Bögge Hartmut,
Haupt Erhard T. K.,
Ghosh Amrita,
López Xavier,
Poblet Josep M.,
Averseng Frédéric,
Che Michel,
Müller Achim
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201305402
Subject(s) - paramagnetism , adaptability , diamagnetism , host (biology) , computer science , service (business) , core (optical fiber) , oxide , chemical physics , chemistry , world wide web , nanotechnology , materials science , physics , condensed matter physics , telecommunications , biology , business , organic chemistry , quantum mechanics , magnetic field , ecology , marketing
Stabilize me : A metal oxide host with a trapped unstable {Mo 36 }‐type polyoxomolybdate guest exhibits independent reduced diamagnetic building blocks and paramagnetic centers (both types with colors other than the dark blue of the Mo centers). The guest in such systems is stabilized especially by a hydrogen‐bond network between the core and the shell.