Structure Elucidation of Host–Guest Complexes of Tartaric and Malic Acids by Quasi‐Racemic Crystallography | Zendy

Lautrette Guillaume | Zendy; Kauffmann Brice | Zendy; Ferrand Yann | Zendy; Aube Christophe | Zendy; Chandramouli Nagula | Zendy; Dubreuil Didier | Zendy; Huc Ivan | Zendy

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Structure Elucidation of Host–Guest Complexes of Tartaric and Malic Acids by Quasi‐Racemic Crystallography

Author(s) -

Lautrette Guillaume,

Kauffmann Brice,

Ferrand Yann,

Aube Christophe,

Chandramouli Nagula,

Dubreuil Didier,

Huc Ivan

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201305364

Subject(s) - foldamer , enantiomer , tartaric acid , diastereomer , malic acid , chemistry , stereochemistry , organic chemistry , citric acid

Racemic on the outside, but not inside : Aromatic‐foldamer hosts are enantiomers and as such prefer to co‐crystallize even though the guests (e.g. L ‐tartaric acid, see picture) in each host are not present as enantiomers. This behavior allows a one‐step structure elucidation of diastereomeric and quasi‐racemic structures in the solid state.

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