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Synthesis and Reactivity of Metal Complexes with Acyclic (Amino)(Ylide)Carbene Ligands
Author(s) -
GonzálezFernández Elisa,
Rust Jörg,
Alcarazo Manuel
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201305311
Subject(s) - ylide , carbene , bimetallic strip , chemistry , isocyanide , reactivity (psychology) , ligand (biochemistry) , reagent , umpolung , metal , combinatorial chemistry , organic chemistry , catalysis , nucleophile , biochemistry , alternative medicine , receptor , pathology , medicine
No cycle required : The straightforward synthesis of acyclic (amino)(ylide)carbene gold complexes was achieved by reaction of isocyanide gold complexes with phosphorus and arsenic ylides as well as electron‐rich olefins. Their ability to form bimetallic species and to act as ligand‐transfer reagents has also been established.