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Facile Access to Tuneable Schwartz’s Reagents: Oxidative Addition Products from the Reaction of Amide NH Bonds with Reduced Zirconocene Complexes
Author(s) -
Haehnel Martin,
Yim Jacky C.H.,
Schafer Laurel L.,
Rosenthal Uwe
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201305246
Subject(s) - reagent , oxidative addition , amide , chemistry , oxidative phosphorylation , combinatorial chemistry , polymer chemistry , organic chemistry , catalysis , biochemistry
On the tracks of Schwartz's reagent : Two zirconocene hydrido amidate complexes are synthesized by formal oxidative addition of amide NH bonds to reduced zirconocene fragments. Insertion reactions with alkenes show a different behavior than Schwartz's reagent by forming branched insertion products. The insertion product and the hydrido complex are characterized by X‐ray analysis.