Facile Access to Tuneable Schwartz’s Reagents: Oxidative Addition Products from the Reaction of Amide NH Bonds with Reduced Zirconocene Complexes | Zendy

Haehnel Martin | Zendy; Yim Jacky C.H. | Zendy; Schafer Laurel L. | Zendy; Rosenthal Uwe | Zendy

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Facile Access to Tuneable Schwartz’s Reagents: Oxidative Addition Products from the Reaction of Amide NH Bonds with Reduced Zirconocene Complexes

Author(s) -

Haehnel Martin,

Yim Jacky C.H.,

Schafer Laurel L.,

Rosenthal Uwe

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201305246

Subject(s) - reagent , oxidative addition , amide , chemistry , oxidative phosphorylation , combinatorial chemistry , polymer chemistry , organic chemistry , catalysis , biochemistry

On the tracks of Schwartz's reagent : Two zirconocene hydrido amidate complexes are synthesized by formal oxidative addition of amide NH bonds to reduced zirconocene fragments. Insertion reactions with alkenes show a different behavior than Schwartz's reagent by forming branched insertion products. The insertion product and the hydrido complex are characterized by X‐ray analysis.

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