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Synthesis of a Dialumene‐Benzene Adduct and Its Reactivity as a Synthetic Equivalent of a Dialumene
Author(s) -
Agou Tomohiro,
Nagata Koichi,
Tokitoh Norihiro
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201305228
Subject(s) - adduct , anthracene , moiety , chemistry , trimethylsilyl , derivative (finance) , benzene , reactivity (psychology) , naphthalene , acetylene , benzene derivatives , medicinal chemistry , stereochemistry , organic chemistry , chemical synthesis , medicine , biochemistry , alternative medicine , pathology , financial economics , economics , in vitro
Bonding with Al : Treatment of a dialumene‐benzene adduct ( 1 ) with naphthalene and anthracene afforded the corresponding dialumene‐arene adducts at room temperature. A 1,2‐dialuminacyclobutene derivative was also obtained by the exchange of the C 6 H 6 moiety of 1 with bis(trimethylsilyl)acetylene. These findings exhibit the potential of 1 as a synthetic equivalent of a dialumene.
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