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Ambident Reactivities of Formaldehyde N , N ‐Dialkylhydrazones
Author(s) -
Maji Biplab,
Troshin Konstantin,
Mayr Herbert
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201305092
Subject(s) - reactivity (psychology) , electrophile , nucleophile , formaldehyde , carbon fibers , computer science , chemistry , service (business) , world wide web , organic chemistry , algorithm , business , catalysis , medicine , alternative medicine , pathology , composite number , marketing
What can attack at carbon? With a nucleophilicity N ≈7 for attack at the azomethine carbon, formaldehyde hydrazones can undergo noncatalyzed reactions at room temperature with electrophiles that have a reactivity parameter E that is greater than −12.
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