Chemoselective Oxidative C(CO)C(methyl) Bond Cleavage of Methyl Ketones to Aldehydes Catalyzed by CuI with Molecular Oxygen | Zendy

Zhang Lin | Zendy; Bi Xihe | Zendy; Guan Xiaoxue | Zendy; Li Xingqi | Zendy; Liu Qun | Zendy; Barry BadruDeen | Zendy; Liao Peiqiu | Zendy

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Chemoselective Oxidative C(CO)C(methyl) Bond Cleavage of Methyl Ketones to Aldehydes Catalyzed by CuI with Molecular Oxygen

Author(s) -

Zhang Lin,

Bi Xihe,

Guan Xiaoxue,

Li Xingqi,

Liu Qun,

Barry BadruDeen,

Liao Peiqiu

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201305010

Subject(s) - catalysis , chemistry , molecular oxygen , oxygen , bond cleavage , oxidative phosphorylation , oxidative cleavage , medicinal chemistry , cleavage (geology) , methyl ketone , photochemistry , organic chemistry , materials science , biochemistry , fracture (geology) , composite material

Aldehyde Termination : A novel copper‐catalyzed transformation from methyl ketones into aldehydes has been accomplished. This method is applicable to a wide range of aromatic and aliphatic methyl ketones and chemoselectively produces aldehydes, accompanied by the release of hydrogen (H 2 ) and carbon dioxide (CO 2 ) as by‐products.

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