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Back Cover: Synthesis, Structure and Gas‐Phase Reactivity of a Silver Hydride Complex [Ag 3 {(PPh 2 ) 2 CH 2 } 3 (μ 3 ‐H)(μ 3 ‐Cl)]BF 4 (Angew. Chem. Int. Ed. 32/2013)
Author(s) -
Zavras Athanasios,
Khairallah George N.,
Connell Timothy U.,
White Jonathan M.,
Edwards Alison J.,
Donnelly Paul S.,
O'Hair Richard A. J.
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201304983
Subject(s) - hydride , sodium borohydride , reactivity (psychology) , cover (algebra) , mass spectrometry , chemistry , gas phase , ligand (biochemistry) , phase (matter) , medicinal chemistry , inorganic chemistry , borohydride , crystallography , organic chemistry , catalysis , metal , biochemistry , receptor , pathology , chromatography , engineering , medicine , mechanical engineering , alternative medicine
Mass Spectrometry Man saves the day! Traveling from his home on planet Gas Phase, he used his ESI‐MS powers to provide G. N. Khairallah, P. S. Donnelly, R. A. J. O'Hair, and co‐workers with vital information for their Communication on page 8391 ff. MS Man's powers revealed the formation of novel silver hydride nanocluster cations in silver salts reduced by sodium borohydride in the presence of a bis(phosphino) ligand, and led the way to the condensed‐phase synthesis, isolation, and characterization of [Ag 3 {(Ph 2 P) 2 CH 2 } 3 (μ 3 ‐H)(μ 3 ‐Cl)]BF 4 ⋅0.5 CHCl 3 .