Phosphine‐Triggered Co‐catenation of :BR and CO on an Iron Atom | Zendy

Braunschweig Holger | Zendy; Ye Qing | Zendy; Vargas Alfredo | Zendy; Radacki Krzysztof | Zendy; Damme Alexander | Zendy

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Phosphine‐Triggered Co‐catenation of :BR and CO on an Iron Atom

Author(s) -

Braunschweig Holger,

Ye Qing,

Vargas Alfredo,

Radacki Krzysztof,

Damme Alexander

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201304972

Subject(s) - catenation , phosphine , chemistry , ligand (biochemistry) , atom (system on chip) , chain (unit) , computer science , stereochemistry , crystallography , combinatorial chemistry , physics , organic chemistry , operating system , catalysis , dna , biochemistry , receptor , astronomy

The chain gang : By treatment of an iron bis(borylene) complex with PCy 3 and subsequent stepwise substitution of a CO ligand by PMe 3 , a catenated 1D OC‐B‐B‐CO chain was generated in the coordination sphere of iron. This is an CO analogue of the recently reported 1D B‐B‐B‐B chain in the iron tetraboron complex [(OC) 2 Fe{BN(SiMe 3 ) 2 } 2 (BDur) 2 ]. Dur=2,3,5,6‐tetramethylphenyl.

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