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Isolation of Neutral Mono‐ and Dinuclear Gold Complexes of Cyclic (Alkyl)(amino)carbenes
Author(s) -
Weinberger David S.,
Melaimi Mohand,
Moore Curtis E.,
Rheingold Arnold L.,
Frenking Gernot,
Jerabek Paul,
Bertrand Guy
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201304820
Subject(s) - alkyl , isolation (microbiology) , computer science , combinatorial chemistry , chemistry , stereochemistry , organic chemistry , biology , bioinformatics
The smallest pieces of gold! Thanks to the presence of two π‐accepting cyclic (alkyl)(amino)carbenes (CAACs),complexes featuring one and two atoms of gold in the formal oxidation state of zero can be isolated.