Tailoring the Window Sizes to Control the Local Concentration and Activity of (salen)Co Catalysts in Plugged Nanochannels of SBA‐15 Materials | Zendy

Shakeri Mozaffar | Zendy; Klein Gebbink Robertus J. M. | Zendy; de Jongh Petra E. | Zendy; de Jong Krijn P. | Zendy

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Tailoring the Window Sizes to Control the Local Concentration and Activity of (salen)Co Catalysts in Plugged Nanochannels of SBA‐15 Materials

Author(s) -

Shakeri Mozaffar,

Klein Gebbink Robertus J. M.,

de Jongh Petra E.,

de Jong Krijn P.

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201304640

Subject(s) - catalysis , window (computing) , hydrolysis , computer science , control (management) , spheres , metal , chemical engineering , chemistry , combinatorial chemistry , materials science , nanotechnology , organic chemistry , physics , world wide web , engineering , astronomy , artificial intelligence

Ship shape! Chiral (salen)Co III complexes (spheres) inside plugged nanochannels of SBA‐15 materials is achieved using a ship‐in‐a‐bottle synthesis technique. The local concentration of the metal complexes and the catalytic activity (such as the hydrolytic kinetic resolution of 1,2‐epoxyalkanes; see scheme) showed a strong dependence on the size of the window.

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