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A Stable Silene Substituted by Strong π‐Donors at the Silicon Center
Author(s) -
Nakata Norio,
Rodriguez Ricardo,
Troadec Thibault,
SaffonMerceron Nathalie,
Sotiropoulos JeanMarc,
Baceiredo Antoine,
Kato Tsuyoshi
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201304594
Subject(s) - silene , silicon , substituent , center (category theory) , chemistry , caryophyllaceae , ligand (biochemistry) , physics , photochemistry , crystallography , stereochemistry , organic chemistry , botany , biology , biochemistry , receptor
Keen to donate : A stable and isolable silene with two π‐donating groups on the silicon center has been synthesized. This silicon‐substituted silene shows totally different π‐substituent effects compared to those of related carbon‐substituted silenes, and it presents intrinsic silene properties with an enhanced electron‐donating character, making it an excellent ligand for transition metals.