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Synthesis of Aryl Trimethylstannanes from Aryl Amines: A Sandmeyer‐Type Stannylation Reaction
Author(s) -
Qiu Di,
Meng He,
Jin Liang,
Wang Shuai,
Tang Shengbo,
Wang Xi,
Mo Fanyang,
Zhang Yan,
Wang Jianbo
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201304579
Subject(s) - aryl , stannane , stille reaction , chemistry , organic chemistry , catalysis , alkyl
Sandmeyer‐type stannylation : Stille coupling is one of the most powerful coupling reactions for CC bond formation, whereas there are only limited methods to access aryl stannane compounds. A mild stannylation process based on a Sandmeyer‐type transformation using aromatic amines as the starting materials is described. DCE: 1,2‐dichloroethane.
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