Selective Reduction of Amides to Amines by Boronic Acid Catalyzed Hydrosilylation | Zendy

Li Yuehui | Zendy; Molina de La Torre Jesús A. | Zendy; Grabow Kathleen | Zendy; Bentrup Ursula | Zendy; Junge Kathrin | Zendy; Zhou Shaolin | Zendy; Brückner Angelika | Zendy; Beller Matthias | Zendy

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Selective Reduction of Amides to Amines by Boronic Acid Catalyzed Hydrosilylation

Author(s) -

Li Yuehui,

Molina de La Torre Jesús A.,

Grabow Kathleen,

Bentrup Ursula,

Junge Kathrin,

Zhou Shaolin,

Brückner Angelika,

Beller Matthias

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201304495

Subject(s) - benzothiophene , hydrosilylation , chemistry , boronic acid , organic chemistry , primary (astronomy) , functional group , catalysis , selective reduction , reduction (mathematics) , combinatorial chemistry , geometry , mathematics , physics , polymer , astronomy , thiophene

Not a ‘B'ore! Benzothiophene‐based boronic acids catalyze the reduction of tertiary, secondary, and primary amides in the presence of a hydrosilane. The reaction demonstrates good functional‐group tolerance.

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