Synthesis of an Imidazolium Phosphanide Zwitterion and Its Conversion into Anionic Imidazol‐2‐ylidene Derivatives | Zendy

Majhi Paresh K. | Zendy; Schnakenburg Gregor | Zendy; Kelemen Zsolt | Zendy; Nyulaszi Laszlo | Zendy; Gates Derek P. | Zendy; Streubel Rainer | Zendy

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Synthesis of an Imidazolium Phosphanide Zwitterion and Its Conversion into Anionic Imidazol‐2‐ylidene Derivatives

Author(s) -

Majhi Paresh K.,

Schnakenburg Gregor,

Kelemen Zsolt,

Nyulaszi Laszlo,

Gates Derek P.,

Streubel Rainer

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201304431

Subject(s) - phosphinidene , zwitterion , adduct , carbene , chemistry , medicinal chemistry , polymer chemistry , organic chemistry , catalysis , molecule

Matter of opinion : The novel zwitterion 1 has been synthesized and studied theoretically and also converted into anionic NHCs 2 . The former can also be described as a phosphinidene adduct of an abnormal N‐heterocyclic carbene ( 1 ′) and, in the same vein, the latter represents a phosphinidene adduct of an anionic N‐heterocyclic dicarbene ( 2 ′).

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