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Synthesis of an Imidazolium Phosphanide Zwitterion and Its Conversion into Anionic Imidazol‐2‐ylidene Derivatives
Author(s) -
Majhi Paresh K.,
Schnakenburg Gregor,
Kelemen Zsolt,
Nyulaszi Laszlo,
Gates Derek P.,
Streubel Rainer
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201304431
Subject(s) - phosphinidene , zwitterion , adduct , carbene , chemistry , medicinal chemistry , polymer chemistry , organic chemistry , catalysis , molecule
Matter of opinion : The novel zwitterion 1 has been synthesized and studied theoretically and also converted into anionic NHCs 2 . The former can also be described as a phosphinidene adduct of an abnormal N‐heterocyclic carbene ( 1 ′) and, in the same vein, the latter represents a phosphinidene adduct of an anionic N‐heterocyclic dicarbene ( 2 ′).