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Slow Magnetic Relaxation in a Co II –Y III Single‐Ion Magnet with Positive Axial Zero‐Field Splitting
Author(s) -
Colacio Enrique,
Ruiz José,
Ruiz Eliseo,
Cremades Eduard,
Krzystek J.,
Carretta Stefano,
Cano Joan,
Guidi Tatiana,
Wernsdorfer Wolfgang,
Brechin Euan K.
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201304386
Subject(s) - ion , magnet , chemistry , magnetic relaxation , relaxation (psychology) , magnetic field , atomic physics , inelastic neutron scattering , neutron , nuclear magnetic resonance , neutron scattering , condensed matter physics , physics , magnetization , nuclear physics , psychology , social psychology , quantum mechanics , organic chemistry
A magnetic Co‐production : The complex [Co(μ‐L)(μ‐OAc)Y(NO 3 ) 2 ] (see structure O red, N blue, C gray), in which the Co II ion exhibits a D value of approximately +45 cm −1 , as determined by magnetic and inelastic neutron scattering experiments, exhibits slow magnetic relaxation and single‐ion magnet behavior.