Unambiguous Characterization of a Photoreactive Ligand‐Loss Intermediate | Zendy

Welby Christine E. | Zendy; Rice Craig R. | Zendy; Elliott Paul I. P. | Zendy

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Unambiguous Characterization of a Photoreactive Ligand‐Loss Intermediate

Author(s) -

Welby Christine E.,

Rice Craig R.,

Elliott Paul I. P.

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201304219

Subject(s) - ligand (biochemistry) , denticity , ruthenium , characterization (materials science) , computer science , tris , chemistry , content delivery , chelation , combinatorial chemistry , information retrieval , world wide web , stereochemistry , nanotechnology , crystallography , organic chemistry , materials science , crystal structure , biochemistry , computer network , catalysis , receptor

Hanging in there : Unprecedented quantitative formation of a long‐lived intermediate 2 that contains a monodentate N N ligand has been observed and the species characterized. Photoreactive ligand loss from a ruthenium(II) tris(chelate) complex 1 leads to 2 , which has a half‐life of 14 hours. Bn=benzyl.

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