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Unambiguous Characterization of a Photoreactive Ligand‐Loss Intermediate
Author(s) -
Welby Christine E.,
Rice Craig R.,
Elliott Paul I. P.
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201304219
Subject(s) - ligand (biochemistry) , denticity , ruthenium , characterization (materials science) , computer science , tris , chemistry , content delivery , chelation , combinatorial chemistry , information retrieval , world wide web , stereochemistry , nanotechnology , crystallography , organic chemistry , materials science , crystal structure , biochemistry , computer network , catalysis , receptor
Hanging in there : Unprecedented quantitative formation of a long‐lived intermediate 2 that contains a monodentate N N ligand has been observed and the species characterized. Photoreactive ligand loss from a ruthenium(II) tris(chelate) complex 1 leads to 2 , which has a half‐life of 14 hours. Bn=benzyl.