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Catalytic Asymmetric Benzidine Rearrangement
Author(s) -
De Chandra Kanta,
Pesciaioli Fabio,
List Benjamin
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201304039
Subject(s) - benzidine , chemistry , computer science , diamine , combinatorial chemistry , stereochemistry , organic chemistry
A chiral Brønsted acid catalyzes the asymmetric benzidine rearrangement of N , N ′‐dinaphthylhydrazines. Different electronically and structurally diverse axially chiral 2,2′‐binaphthyl diamine (BINAM) derivatives are obtained with high enantioselectivity.