Asymmetric Catalytic 1,6‐Conjugate Addition/Aromatization of  para ‐Quinone Methides: Enantioselective Introduction of Functionalized Diarylmethine Stereogenic Centers | Zendy

Chu WenDao | Zendy; Zhang LeFen | Zendy; Bao Xu | Zendy; Zhao XianHe | Zendy; Zeng Chao | Zendy; Du JiYuan | Zendy; Zhang GuoBiao | Zendy; Wang FangXin | Zendy; Ma XiaoYan | Zendy; Fan ChunAn | Zendy

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Asymmetric Catalytic 1,6‐Conjugate Addition/Aromatization of para ‐Quinone Methides: Enantioselective Introduction of Functionalized Diarylmethine Stereogenic Centers

Author(s) -

Chu WenDao,

Zhang LeFen,

Bao Xu,

Zhao XianHe,

Zeng Chao,

Du JiYuan,

Zhang GuoBiao,

Wang FangXin,

Ma XiaoYan,

Fan ChunAn

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201303928

Subject(s) - enantioselective synthesis , stereocenter , conjugate , aromatization , quinone , computer science , catalysis , chemistry , combinatorial chemistry , world wide web , organic chemistry , mathematics , mathematical analysis

It′s just a phase : The title reaction sequence of para ‐quinone methides ( p ‐QMs) has been developed with malonates under phase‐transfer catalysis. The reaction also offers an alternative route to asymmetric construction of diarylmethine stereocenters in excellent enantioselectivities and high yields.

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