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The X‐ray Crystal Structure of a Cuprate–Carbonyl π‐Complex
Author(s) -
Bertz Steven H.,
Hardin Richard A.,
Heavey Thomas J.,
Ogle Craig A.
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201303783
Subject(s) - cuprate , computer science , scheme (mathematics) , service (business) , crystal (programming language) , information retrieval , world wide web , physics , programming language , business , mathematics , optoelectronics , doping , marketing , mathematical analysis
Why is it π? The first X‐ray crystal structure of a cuprate–carbonyl π‐complex has been obtained for the intermediate prepared from Me 2 CuLi and fluorenone (see scheme). It is also the first structure of a π‐complex between an organocuprate and a double bond of any kind.