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Shape‐Controlled Synthesis of Surface‐Clean Ultrathin Palladium Nanosheets by Simply Mixing a Dinuclear Pd I Carbonyl Chloride Complex with H 2 O
Author(s) -
Li Huan,
Chen Guangxu,
Yang Huayan,
Wang Xingli,
Liang Jinghong,
Liu Pengxin,
Chen Mei,
Zheng Nanfeng
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201303772
Subject(s) - palladium , mixing (physics) , nanocrystal , catalysis , chloride , chemical engineering , materials science , surface modification , nanotechnology , chemistry , inorganic chemistry , organic chemistry , metallurgy , physics , quantum mechanics , engineering
Simple shape control : Ultrathin Pd nanosheets are readily fabricated by simply mixing [Pd 2 (μ‐CO) 2 Cl 4 ] 2− with H 2 O at ambient temperature. The as‐prepared Pd nanosheets are surface clean and serve as an excellent platform to evaluate the effect of organic capping agents on the catalytic and electrocatalytic properties of Pd nanocrystals.