Direct Oxidative Allylic and Vinylic Amination of Alkenes through Selenium Catalysis | Zendy

Trenner Johanna | Zendy; Depken Christian | Zendy; Weber Thomas | Zendy; Breder Alexander | Zendy

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Direct Oxidative Allylic and Vinylic Amination of Alkenes through Selenium Catalysis

Author(s) -

Trenner Johanna,

Depken Christian,

Weber Thomas,

Breder Alexander

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201303662

Subject(s) - amination , allylic rearrangement , selenium , chemistry , oxidative phosphorylation , catalysis , organic chemistry , combinatorial chemistry , biochemistry

Bringing “N” into the game : The direct chemoselective nitrogenation of unactivated alkenes can be achieved through oxidative selenium catalysis (see scheme). This method provides a broad variety of allylic imides in yields of up to 89 % using N ‐fluorobenzenesulfonimide (NFSI) as the terminal oxidant and nitrogen source. Furthermore, an unprecedented selenium‐catalyzed vinylic C(sp 2 )–H nitrogenation was discovered.

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