Chiral Scandium(III)‐Catalyzed Enantioselective α‐Arylation of N‐Unprotected 3‐Substituted Oxindoles with Diaryliodonium Salts | Zendy

Guo Jing | Zendy; Dong Shunxi | Zendy; Zhang Yulong | Zendy; Kuang Yulong | Zendy; Liu Xiaohua | Zendy; Lin Lili | Zendy; Feng Xiaoming | Zendy

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Chiral Scandium(III)‐Catalyzed Enantioselective α‐Arylation of N‐Unprotected 3‐Substituted Oxindoles with Diaryliodonium Salts

Author(s) -

Guo Jing,

Dong Shunxi,

Zhang Yulong,

Kuang Yulong,

Liu Xiaohua,

Lin Lili,

Feng Xiaoming

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201303602

Subject(s) - scandium , enantioselective synthesis , catalysis , electrophile , aryl , reactivity (psychology) , chemistry , combinatorial chemistry , carbon fibers , lewis acids and bases , organic chemistry , computer science , alkyl , medicine , alternative medicine , pathology , algorithm , composite number

Catalytic asymmetric α‐arylation of N‐unprotected 3‐substituted oxindoles with diaryliodonium salts has been realized by a chiral Lewis acid promoted electrophilic addition and aryl‐rearrangement process. Single C3‐arylated products containing a quaternary carbon center were generated in high enantioselectivity and reactivity.

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