Hydrogen Bonding and Alcohol Effects in Asymmetric Hypervalent Iodine Catalysis: Enantioselective Oxidative Dearomatization of Phenols | Zendy

Uyanik Muhammet | Zendy; Yasui Takeshi | Zendy; Ishihara Kazuaki | Zendy

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Hydrogen Bonding and Alcohol Effects in Asymmetric Hypervalent Iodine Catalysis: Enantioselective Oxidative Dearomatization of Phenols

Author(s) -

Uyanik Muhammet,

Yasui Takeshi,

Ishihara Kazuaki

Publication year - 2013

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201303559

Subject(s) - hypervalent molecule , enantioselective synthesis , intramolecular force , catalysis , chemistry , phenols , hydrogen bond , alcohol , iodine , phenol , organic chemistry , oxidative phosphorylation , combinatorial chemistry , molecule , biochemistry

Iodine chooses : A conformationally flexible C 2 ‐symmetric organoiodine(III) catalyst for the highly enantioselective catalytic oxidative dearomatization of phenols has been developed. Catalysis is controlled by intramolecular hydrogen‐bonding interactions and additional achiral alcohols.

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