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Hydrogen Bonding and Alcohol Effects in Asymmetric Hypervalent Iodine Catalysis: Enantioselective Oxidative Dearomatization of Phenols
Author(s) -
Uyanik Muhammet,
Yasui Takeshi,
Ishihara Kazuaki
Publication year - 2013
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201303559
Subject(s) - hypervalent molecule , enantioselective synthesis , intramolecular force , catalysis , chemistry , phenols , hydrogen bond , alcohol , iodine , phenol , organic chemistry , oxidative phosphorylation , combinatorial chemistry , molecule , biochemistry
Iodine chooses : A conformationally flexible C 2 ‐symmetric organoiodine(III) catalyst for the highly enantioselective catalytic oxidative dearomatization of phenols has been developed. Catalysis is controlled by intramolecular hydrogen‐bonding interactions and additional achiral alcohols.